Express each of the following numbers in exponential notation with correct significant figures:
(a) 704
(b) 0.03344
(c) 547.9
(d) 22086
(e) 1000.00
(f) 0.0000000651
(g) 0.007157
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Chemistry 2e · 1.5 Measurement Uncertainty, Accuracy, and Precision
6 problems from the book, with its answers. Check your working, or have any of them explained to you on the whiteboard.
To count significant figures, start at the first nonzero digit. Zeros between nonzero digits count, trailing zeros after a decimal point count, and leading zeros never do; a number like 1000 is ambiguous, so write it in scientific notation to show what was measured. When you multiply or divide, keep as many significant figures as the measurement with the fewest. When you add or subtract, keep as many decimal places as the measurement with the fewest. Exact numbers, like 60 seconds in a minute, limit nothing. When the digit you drop is exactly 5, this book rounds to the even neighbour: 0.445 becomes 0.44. The usual mistakes: using the multiplication rule for a sum, and rounding at every step instead of once at the end.
Exercises 45
Express each of the following numbers in exponential notation with correct significant figures:
(a) 704
(b) 0.03344
(c) 547.9
(d) 22086
(e) 1000.00
(f) 0.0000000651
(g) 0.007157
Exercises 47
Indicate whether each of the following can be determined exactly or must be measured with some degree of uncertainty:
(a) the number of seconds in an hour
(b) the number of pages in this book
(c) the number of grams in your weight
(d) the number of grams in 3 kilograms
(e) the volume of water you drink in one day
(f) the distance from San Francisco to Kansas City
Exercises 49
How many significant figures are contained in each of the following measurements?
(a) 53 cm
(b) 2.05 10⁸ m
(c) 86,002 J
(d) 9.740 10⁴ m/s
(e) 10.0613 m³
(f) 0.17 g/mL
(g) 0.88400 s
Exercises 51
Round off each of the following numbers to two significant figures:
(a) 0.436
(b) 9.000
(c) 27.2
(d) 135
(e) 1.497 10⁻³
(f) 0.445
Exercises 53
Perform the following calculations and report each answer with the correct number of significant figures.
(a) 628 342
(b) (5.63 10²) (7.4 10³)
(c)
(d) 8119 0.000023
(e) 14.98 + 27,340 + 84.7593
(f) 42.7 + 0.259
Exercises 55
Consider the results of the archery contest shown in this figure.
(a) Which archer is most precise?
(b) Which archer is most accurate?
(c) Who is both least precise and least accurate?

The tutor teaches the whole section, drawing it out step by step and answering your questions as you go.